Episode #539

Why Can’t This Battery Fly? The Science of Li-ion Safety

Why are loose batteries a "no-go" for shipping? Herman and Corn explore the volatile science and strict laws behind lithium-ion logistics.

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In the latest episode of My Weird Prompts, brothers Herman and Corn Poppleberry tackle a question that has likely puzzled every modern traveler and online shopper: why are the rules surrounding lithium-ion batteries so incredibly specific and, at times, seemingly contradictory? The discussion was sparked by their housemate Daniel, who, while browsing for DIY tools, noticed that international retailers have no problem shipping devices with built-in batteries but often flat-out refuse to ship loose, individual battery cells.

The UN Classification Puzzle

Herman, the more technically inclined of the duo, begins by explaining that the movement of batteries is governed by a strict set of international standards established by the United Nations Committee of Experts on the Transport of Dangerous Goods. To the average consumer, a battery is just a battery. However, in the eyes of global logistics, they are divided into two very different categories: UN 3480 and UN 3481.

UN 3480 refers to lithium-ion batteries shipped by themselves. These are considered "fully regulated Class 9 Dangerous Goods." Because they lack the protective shell of a device, they are subject to rigorous packaging requirements, including specialized drop-tested boxes and mandatory state-of-charge limits—currently capped at 30% for air cargo. UN 3481, conversely, covers batteries contained within or packed with equipment. As Herman points out, when a battery is "clicked into" a tool or sealed inside a laptop, the device itself acts as a protective chassis. This physical barrier prevents the battery from being punctured and, more importantly, keeps the terminals isolated to prevent short circuits.

The Anatomy of a Thermal Runaway

The primary reason for these stringent rules is a phenomenon known as thermal runaway. Corn and Herman describe this as a catastrophic chemical feedback loop. Inside a lithium-ion cell, a thin separator keeps the anode and cathode apart. If this separator is compromised—via a crush, a puncture, or an internal short circuit—the stored energy is released instantly as heat.

This heat causes the internal chemicals to break down, which in turn generates more heat and, crucially, its own oxygen. Herman notes that once a battery reaches this state, it can hit temperatures of over 700 degrees Celsius in seconds. Because the fire provides its own fuel and oxygen, it cannot be extinguished by traditional "smothering" methods. It is a chemical fire that must be cooled down to stop the chain reaction from spreading to adjacent cells.

Why Your Power Bank Stays in the Cabin

The conversation then pivots to a common travel frustration: why airlines forbid batteries in checked luggage but require them in the cabin. At first glance, it seems counterintuitive. Why would you want a potential fire in the passenger cabin rather than the isolated cargo hold?

The brothers explain that this is a calculated safety trade-off based on detection and suppression. In the cabin, a smoking battery is noticed immediately by passengers or crew. Flight attendants are equipped with specialized high-temperature containment bags and can use water or non-flammable liquids to cool the device. While water is usually avoided for electrical fires, in the case of a lithium-ion runaway, the primary goal is heat reduction to prevent the fire from "jumping" to other cells.

In the cargo hold, however, a battery fire is a different beast entirely. While modern planes use Halon 1301 gas to suppress fires in the hold, Herman explains that Halon is ineffective against lithium-ion fires. While it may knock down open flames, it cannot stop the internal chemical reaction. Furthermore, the FAA has found that the buildup of gases released by failing batteries—such as hydrogen—can lead to pressure increases capable of compromising the aircraft's structure. By keeping batteries in the cabin, the aviation industry ensures that any incident is "manageable" rather than a hidden, un-extinguishable catastrophe in the belly of the plane.

The "Gray Area" of Small Electronics

Corn raises the question of everyday items like electric toothbrushes or shavers, which many people habitually pack in their checked bags. Herman clarifies that while most airlines allow small devices with built-in batteries to be checked (provided they are completely powered down), it remains a gray area. The ultimate risk factor is the "loose" battery—the spare camera battery or the power bank. These items have exposed terminals that can easily short-circuit if they come into contact with metal objects like keys, coins, or zippers.

Advanced Detection in the Skies

To wrap up the discussion, Herman provides a deep dive into how aircraft actually detect these threats. Cargo holds are classified as "Class C" compartments, meaning they must have independent smoke detection and built-in suppression. These systems use optical sensors that detect light scattering caused by smoke particles.

Once smoke is detected, pilots initiate a two-stage suppression strategy. First, a "high-rate discharge" of Halon floods the hold to kill any immediate flames. This is followed by a "low-rate discharge" that slowly leaks Halon for the remainder of the flight, maintaining a concentration high enough to keep the fire suppressed until the plane can make an emergency landing.

Final Takeaways

The episode serves as a reminder that the seemingly "annoying" rules of travel and shipping are written in the language of chemistry and safety engineering. Whether it is the UN 3480 classification or the ban on checked power banks, these regulations exist because lithium-ion batteries are essentially high-density energy storage units that require respect. As Herman and Corn conclude, the safest place for your battery is where you can see it, and the safest way to ship it is inside the device it was meant to power.

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Episode #539: Why Can’t This Battery Fly? The Science of Li-ion Safety

Corn
Hey everyone, welcome back to My Weird Prompts. I am Corn, and I am here with my brother, the man who probably has a spreadsheet for every battery in this house.
Herman
Herman Poppleberry at your service. And you are not wrong, Corn. I actually checked the health of our laptop batteries just last Tuesday. It is a necessary habit.
Corn
Of course it is. Well, we have a really interesting one today. Our housemate Daniel sent us a voice note from the couch. He is still fighting off that cold, so he has had some time to do some deep thinking and some online shopping. He was looking for a heat gun for some do it yourself projects and noticed that AliExpress and other retailers have these really specific, almost confusing rules about shipping batteries.
Herman
It is a classic logistics puzzle. Daniel noticed that if the battery is loose or detachable, it is often a no go for international shipping, but if it is built into the device, it comes right through. And he also asked about how this works when we are actually flying, like why we can carry batteries in the cabin but not in our checked luggage.
Corn
It is one of those things we all just kind of accept as a rule of travel, like taking off your shoes at security, but the actual science and the regulatory logic behind it are pretty intense. I mean, we are talking about high energy density devices that can essentially become miniature blowtorches if things go wrong.
Herman
Exactly. And I love that Daniel brought this up because it touches on everything from chemical engineering to international maritime law and aviation safety. There is a whole world of hazard classifications that determine how these little power bricks move around the globe.
Corn
So let us start with the shipping side of things. Why does AliExpress or Amazon for that matter care so much if the battery is inside the tool or next to it in the box? To a normal person, it is the same amount of lithium, right?
Herman
You would think so, but from a regulatory standpoint, it changes everything. This comes down to the United Nations Committee of Experts on the Transport of Dangerous Goods. They have these specific numbers called UN numbers that classify materials. For lithium ion batteries, the big ones are UN thirty four eighty and UN thirty four eighty one.
Corn
Okay, break those down for me. What is the difference?
Herman
UN thirty four eighty is for lithium ion batteries shipped by themselves. Just the batteries. UN thirty four eighty one is for lithium ion batteries contained in equipment or packed with equipment. Now, the reason retailers like AliExpress struggle with the loose batteries, the UN thirty four eighty category, is that they are considered fully regulated Class Nine Dangerous Goods.
Corn
Class Nine. That sounds serious.
Herman
It is. When you ship loose batteries, the packaging requirements are much stricter. You need specialized boxes that have been drop tested, specific labeling, and the shipping costs skyrocket because many passenger planes will not carry them at all. They have to go on dedicated cargo aircraft. Also, as of the latest ICAO updates, loose batteries shipped as cargo must be at a state of charge of thirty percent or less. That is hard for a factory to manage and verify for every single unit.
Corn
So if I buy a heat gun and the battery is already clicked into the handle, or even just inside the casing, it falls under that other category, UN thirty four eighty one?
Herman
Precisely. When a battery is inside a device, the device itself acts as a protective shell. It prevents the battery from being crushed or punctured easily. But more importantly, it prevents the battery terminals from touching something metallic and short circuiting. If you have a bunch of loose batteries in a box and they shift during transit, and a positive terminal touches a negative terminal via a stray piece of metal or even another battery, you get a short. That leads to heat, which leads to thermal runaway.
Corn
Thermal runaway. That is the term everyone hears but maybe does not fully understand. What is actually happening inside the cell when that starts?
Herman
It is a feedback loop. Think of it as a chemical fire that provides its own fuel and its own oxygen. If a cell gets too hot, the separator between the anode and the cathode melts. Once that happens, all that stored energy is released at once as heat. That heat then causes the neighboring cells to fail, which releases more heat. It is a chain reaction that can reach temperatures over seven hundred degrees Celsius in seconds.
Corn
Seven hundred degrees. That is hot enough to melt aluminum.
Herman
Oh, easily. And the scary part is that a lithium ion fire produces its own oxygen through the breakdown of the cathode material. So you cannot just smother it like a normal fire. You can cut off the outside air, and it will just keep screaming along.
Corn
So when Daniel sees that the built in battery is okay to ship, it is because the engineers have essentially designed a safety cage around that potential fire. The device casing provides physical protection and ensures the terminals stay isolated.
Herman
Right. And there is another layer to this. For shipping, built in batteries often fall under what they call Section Two of the packing instructions. If the battery is under a certain capacity, like one hundred watt hours for a battery pack or twenty watt hours for a single cell, and it is inside a device, the regulations are much more relaxed. You do not need the full dangerous goods documentation or the expensive specialized handling. That is why AliExpress can ship you a phone or a laptop with no problem, but they will cancel your order for five loose eighteen six hundred fifty cells.
Corn
That makes a lot of sense. It is about the risk of a short circuit during the chaos of shipping and handling. But let us pivot to Daniel's other question, which is about flying. This is where it gets really counterintuitive for a lot of people. If I have a power bank, the airline insists it stays in my carry on. They absolutely do not want it in the cargo hold. But wait, isn't the cargo hold where the fire suppression systems are? Why would they want the fire in the cabin with the people?
Herman
This is one of the most fascinating parts of aviation safety logic. It sounds backwards, but it is actually a very calculated decision. There are two main reasons. The first is detection. If a battery starts to smoke in a carry on bag in the overhead bin, someone is going to smell it or see it almost immediately. The flight attendants are trained for this. They have specialized fire containment bags, which are basically heavy duty, high temperature sacks they can drop the device into.
Corn
So human eyes and noses are the best smoke detectors we have.
Herman
Exactly. Fast detection is key. The second reason is the type of fire. Like I mentioned, lithium fires are incredibly difficult to put out. In the cabin, the crew can use water or a non flammable liquid to cool the battery. While water is usually a bad idea for electrical fires, for a lithium ion battery in thermal runaway, the goal is actually to pull heat away from the neighboring cells to stop the chain reaction. You are essentially dousing it to keep it from spreading.
Corn
Okay, so if that same battery is in the cargo hold, what happens? There aren't any flight attendants down there with water bottles.
Herman
That is the problem. Most modern passenger planes use a fire suppression gas called Halon thirteen zero one in their cargo holds. Halon is amazing at putting out a suitcase that is on fire or a box of clothes. It works by chemically interrupting the combustion process. However, Halon does not work on lithium ion batteries.
Corn
Wait, it doesn't work at all?
Herman
It will put out the open flames, but because the battery is undergoing a chemical reaction that generates its own heat and oxygen internally, the Halon cannot stop the thermal runaway itself. The battery will keep cooking, and once the Halon concentration in the hold drops, the fire can just flare right back up.
Corn
That is terrifying. So you have a fire that the automated system cannot actually extinguish, and it is hidden under hundreds of suitcases where nobody can see it until it is potentially too late.
Herman
Precisely. In twenty thirteen, the Federal Aviation Administration did a series of tests where they put a bunch of lithium batteries in a simulated cargo hold and triggered a thermal runaway. They found that the Halon suppressed the fire, but the pressure from the gases released by the batteries actually blew the door off the cargo hold. The batteries release hydrogen and other flammable gases as they fail. If those gases build up and then find a spark, you get an explosion.
Corn
So the policy of keeping batteries in the cabin is basically saying, we would rather have a fire we can see and fight manually than a hidden fire that might blow a hole in the side of the plane.
Herman
That is exactly the trade off. It is about manageability. In the cabin, it is a manageable incident. In the hold, it is a potential catastrophe.
Corn
Now, Daniel mentioned his electric toothbrush. He said he usually packs that in his checked luggage. And a lot of people do that with electric shavers or toothbrushes. Is that actually a violation of the rules, or is there a loophole there?
Herman
It is generally allowed, but it is a bit of a gray area. Most airlines allow small devices with built in batteries in checked bags as long as they are completely turned off and protected from accidental activation. You do not want your toothbrush vibrating for eight hours and overheating. But even then, safety experts will tell you that the safest place for any lithium battery, no matter how small, is in the cabin.
Corn
So the rule is really about the loose batteries again. The power banks, the spare camera batteries, the loose cells for a flashlight. Those are the high risk items because they have exposed terminals and no outer protective casing from a tool or a device.
Herman
Right. If you have a spare battery and the terminals touch a coin or a zipper in your suitcase, that is your ignition source right there. That is why if you must carry spare batteries, the recommendation is always to put them in individual plastic bags or put tape over the terminals.
Corn
I want to go back to the cargo hold for a second. You mentioned Halon. I am curious about the actual tech down there. How does a plane even know there is a fire in the hold? It is not like there is a guy with a thermal camera watching the suitcases.
Herman
It is actually a very sophisticated system. Most cargo holds are what they call Class C compartments. To be a Class C hold, you need two things: a separate smoke detection system and a built in fire suppression system. The smoke detectors are usually optical. They use light scattering. Basically, a beam of light is sent across a sensor, and if smoke particles enter the chamber, they scatter the light onto a receiver, which triggers the alarm in the cockpit.
Corn
And once that alarm goes off, what does the pilot do? Do they just hit a big red button?
Herman
Pretty much. They have a switch that discharges the first bottle of Halon. This is called the high rate discharge. It floods the cargo hold immediately to knock down any flames. But here is the clever part: they also have a second bottle, or a series of bottles, called the low rate discharge. This slowly leaks Halon into the hold for the rest of the flight, sometimes for up to several hours, to keep the concentration high enough to prevent the fire from re igniting while the pilot looks for the nearest airport to land.
Corn
That is incredible. So it is not just one blast; it is a sustained chemical environment designed to keep the fire asleep until they can get on the ground.
Herman
Exactly. But again, that system was designed for burning luggage, not for lithium batteries. This is why the International Civil Aviation Organization actually banned the transport of lithium ion batteries as cargo on passenger planes back in twenty sixteen. If you see a big pallet of iPhones on a plane, that plane is almost certainly a dedicated cargo freighter, not the flight you are taking to visit your grandma.
Corn
That is a huge distinction. So the batteries we are carrying in our pockets are literally the only lithium batteries on the entire passenger plane, aside from what is built into the aircraft's own systems.
Herman
For the most part, yes. And even the aircraft's own batteries have been redesigned. Remember the Boeing seven eighty seven Dreamliner issues back in twenty thirteen? They had those battery fires that grounded the whole fleet. The fix was not just making the batteries better; it was encasing the entire battery in a heavy stainless steel box with a vent pipe that leads directly to the outside of the aircraft. So if the battery fails, the fire and the toxic gases are literally piped overboard.
Corn
Talk about a second order effect. You have to design a chimney for your battery just in case it decides to self destruct.
Herman
It is the only way to be sure.
Corn
So, looking forward, do you think these regulations are going to get even stricter? I mean, we are putting lithium batteries in everything now. I saw a heated jacket the other day that uses a massive power bank. People are wearing these things on planes.
Herman
It is a constant battle between energy density and safety. The more energy we cram into a small space, the more dangerous that space becomes. There is a lot of hope for solid state batteries. These would replace the flammable liquid electrolyte with a solid material that is much more stable. If we can get solid state batteries into the mainstream, a lot of these shipping and travel restrictions might actually vanish because the risk of thermal runaway would be almost zero.
Corn
That would be a game changer for logistics. Imagine AliExpress being able to ship whatever they want without worrying about the plane catching fire.
Herman
It would save billions in shipping costs. But until then, we are stuck with the rules. And honestly, the rules are there for a reason. I have seen videos of eighteen six hundred fifty cells failing, and it is not a fire you want to be near, especially at thirty five thousand feet.
Corn
You know, it occurs to me that there is a bit of a psychological gap here. We use these devices every day. I am holding a phone right now, you have a laptop on your lap. We trust them completely. But the moment they go into a cardboard box or a suitcase, they become Hazmat.
Herman
It is all about the environment. In your hand, you are monitoring the device. If your phone gets hot, you put it down. You notice if the screen starts to bulge because the battery is swelling. But in a shipping container at the bottom of a pile of ten thousand other boxes, there is no one to notice those early warning signs. Logistics is all about planning for the worst case scenario in an unmonitored environment.
Corn
That is a great way to put it. It is the transition from a monitored personal item to an unmonitored piece of cargo.
Herman
Precisely. And for our listeners, there is a practical takeaway here. If you are buying electronics from overseas, and you see that the shipping is unusually expensive or it says it has to go by sea, it is probably because of that UN thirty four eighty classification. It is not just the retailer being difficult; it is them following international law to make sure the plane stays in the air.
Corn
And if you are packing for a trip, take the extra two minutes to move your batteries to your carry on. Even the small ones. It is not just about following the rules; it is about giving the flight crew a fighting chance if something goes sideways.
Herman
And check your watt hours. Most airlines have a limit of one hundred watt hours for a single battery. You can sometimes bring larger ones, up to one hundred sixty watt hours, but you usually need prior approval from the airline. If you try to bring a massive professional cinema camera battery or a huge e bike battery, they might stop you at the gate.
Corn
One hundred watt hours. How do people find that number? It is usually not written in big letters on the side.
Herman
You have to do a little bit of math, which I know is everyone's favorite part of travel. Most batteries list milliamp hours and volts. To get watt hours, you multiply the amp hours by the nominal voltage. Now, here is the trick: most power banks use internal cells rated at three point seven volts. So a twenty thousand milliamp hour power bank is actually seventy four watt hours. You only hit that one hundred watt hour limit when you get up to about twenty seven thousand milliamp hours.
Corn
Twenty seven thousand. Okay, so my standard phone brick is well within the limit.
Herman
Exactly. And most manufacturers are starting to print the watt hours on the label now because they know people need it for security.
Corn
This has been such a deep dive into something I usually don't think twice about. It is amazing how much engineering and law is packed into that one little rule about not putting batteries in your checked bag.
Herman
It is the hidden infrastructure of safety. We only notice it when it gets in the way of our shopping or our packing, but it is the reason air travel remains as safe as it is.
Corn
Well, I think we have covered the bases for Daniel. Hopefully, this gives him some clarity while he is resting up on the couch. And maybe he can find a heat gun that comes with the battery already installed so he doesn't have to worry about the shipping drama.
Herman
Or he can just buy the tool locally and save himself the headache. But where is the fun in that?
Corn
Exactly. We like the weird prompts. We like the logistics puzzles.
Herman
We really do. And hey, if you are listening and you have found this useful, or if you have your own weird question about how the world works, please reach out. You can find us at myweirdprompts.com. There is a contact form there, and we love hearing from you.
Corn
And if you have a second, leave us a review on Spotify or wherever you get your podcasts. It really does help other curious people find the show. We are up to episode five hundred thirty now, and it is all thanks to this community.
Herman
It really is. This has been My Weird Prompts. I am Herman Poppleberry.
Corn
And I am Corn. Thanks for listening, and we will talk to you in the next one.
Herman
Goodbye everyone.

This episode was generated with AI assistance. Hosts Herman and Corn are AI personalities.

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